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Information card for entry 4089342
Preview
Coordinates | 4089342.cif |
---|---|
Original paper (by DOI) | HTML |
Common name | [RuTp(kappa^2^(C,P)=C(CH~2~Ph)N(Ph)PPh~2~) (kappa^1^(P)-PPh~2~NHPh)]SbF~6~.2C~6~H~5~F (14a.2C~6~H~5~F) |
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Formula | C65 H58 B F8 N8 P2 Ru Sb |
Calculated formula | C65 H58 B F8 N8 P2 Ru Sb |
SMILES | [Ru]123([P](c4ccccc4)(c4ccccc4)N(c4ccccc4)C=3Cc3ccccc3)([P](c3ccccc3)(c3ccccc3)Nc3ccccc3)[n]3n([BH](n4[n]1ccc4)n1[n]2ccc1)ccc3.[Sb](F)(F)(F)(F)([F-])F.Fc1ccccc1.Fc1ccccc1 |
Title of publication | Reactions of the Cationic Fragments [RuCp(PPh2NHR)2]+and [RuTp(PPh2NHR)2]+(R = Ph,n-Pr) with Alkynes: Formation of Four-Membered Azaphosphacarbenes |
Authors of publication | Pavlik, Sonja; Mereiter, Kurt; Puchberger, Michael; Kirchner, Karl |
Journal of publication | Organometallics |
Year of publication | 2005 |
Journal volume | 24 |
Journal issue | 14 |
Pages of publication | 3561 |
a | 11.403 ± 0.002 Å |
b | 17.341 ± 0.004 Å |
c | 31.492 ± 0.007 Å |
α | 90° |
β | 96.726 ± 0.007° |
γ | 90° |
Cell volume | 6184 ± 2 Å3 |
Cell temperature | 300 ± 2 K |
Ambient diffraction temperature | 300 ± 2 K |
Number of distinct elements | 8 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/c 1 |
Hall space group symbol | -P 2ybc |
Residual factor for all reflections | 0.2321 |
Residual factor for significantly intense reflections | 0.0874 |
Weighted residual factors for significantly intense reflections | 0.193 |
Weighted residual factors for all reflections included in the refinement | 0.2634 |
Goodness-of-fit parameter for all reflections included in the refinement | 0.956 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4089342.html
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