Synthesis of Silicon-Functionalized (Silylmethyl)silanes and α,ω-Dichlorocarbosilanes Using the TMOP (2,4,6-Trimethoxyphenyl) Protecting Group: (TMOP)Me2SiCH2Cl and (TMOP)2MeSiCH2Cl as Reagents To Introduce the ClMe2SiCH2, MeOMe2SiCH2, or Cl2MeSiCH2 Group by Nucleophilic Substitution at Silicon
Authors of publication
Laskowski, Nadine; Reis, Eva-Maria; Kötzner, Lisa; Baus, Johannes A.; Burschka, Christian; Tacke, Reinhold
Journal of publication
Organometallics
Year of publication
2013
Journal volume
32
Journal issue
11
Pages of publication
3269
a
12.101 ± 0.003 Å
b
15.026 ± 0.003 Å
c
15.174 ± 0.003 Å
α
94.85 ± 0.03°
β
109.23 ± 0.03°
γ
96.25 ± 0.03°
Cell volume
2568.3 ± 1.1 Å3
Cell temperature
173 ± 2 K
Ambient diffraction temperature
173 ± 2 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0521
Residual factor for significantly intense reflections
0.0431
Weighted residual factors for significantly intense reflections
0.1342
Weighted residual factors for all reflections included in the refinement
0.1387
Goodness-of-fit parameter for all reflections included in the refinement
