Information card for entry 4089527

Structure parameters

• Formula: C16 H16 O10 P2 W2
• Calculated formula: C16 H16 O10 P2 W2
• SMILES: [W]([PH]([W](C#[O])(C#[O])(C#[O])(C#[O])C#[O])[P+](CC)(CC)CC)(C#[O])(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Versatile Reactivity of Bridged Pentelidene Complexes toward Secondary and Tertiary Phosphines
• Authors of publication: Stubenhofer, Markus; Kuntz, Christian; Bodensteiner, Michael; Timoshkin, Alexey Y.; Scheer, Manfred
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 12
• Pages of publication: 3521
• a: 10.1037 ± 0.0005 Å
• b: 17.3031 ± 0.0006 Å
• c: 13.5435 ± 0.0007 Å
• α: 90°
• β: 98.577 ± 0.005°
• γ: 90°
• Cell volume: 2341.27 ± 0.19 ų
• Cell temperature: 123 ± 1 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 5
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.066
• Residual factor for significantly intense reflections: 0.062
• Weighted residual factors for significantly intense reflections: 0.157
• Weighted residual factors for all reflections included in the refinement: 0.1618
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No