Information card for entry 4100540

Structure parameters

• Formula: C39 H63 B2 F8 N3 Os P2
• Calculated formula: C39 H63 B2 F8 N3 Os P2
• SMILES: [Os]([P](C(C)C)(C(C)C)C(C)C)([P](C(C)C)(C(C)C)C(C)C)([N]#CC)([N]#CC)([N]#CC)=C\C=C(/c1ccccc1)c1ccccc1.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-]
• Title of publication: Hydride-Alkenycarbyne to Alkenylcarbene Transformation in Bisphosphine-Osmium Complexes
• Authors of publication: Bolaño, T.; Castarlenas, R.; Esteruelas, M. A.; Modrego, J.; Oñate, E.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2005
• a: 18.2946 ± 0.0017 Å
• b: 10.9593 ± 0.001 Å
• c: 21.991 ± 0.002 Å
• α: 90°
• β: 92.074 ± 0.002°
• γ: 90°
• Cell volume: 4406.2 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No