Information card for entry 4100732

Structure parameters

• Formula: C43 H47 P4 Rh
• Calculated formula: C43 H47 P4 Rh
• SMILES: [RhH]12([P](C)(C)C)([P](C)(C)C)C(=P(c3c1cccc3)(c1ccccc1)c1ccccc1)[P+](c1c2cccc1)(c1ccccc1)c1ccccc1
• Title of publication: Chelate and pincer carbene complexes of rhodium and platinum derived from hexaphenylcarbodiphosphorane, Ph3P=C=PPh3
• Authors of publication: Kubo, Kazuyuki; Jones, Nathan D.; Ferguson, Michael J.; McDonald, Robert; Cavell, Ronald G.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2005
• a: 11.479 ± 0.003 Å
• b: 19.374 ± 0.005 Å
• c: 17.234 ± 0.005 Å
• α: 90°
• β: 91.107 ± 0.005°
• γ: 90°
• Cell volume: 3832.1 ± 1.7 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No