Information card for entry 4101771

Structure parameters

• Common name: [Rh((C6H4)PPh2)(trop2PPh)]
• Formula: C112 H92 O P4 Rh2
• Calculated formula: C114.465 H82 P4 Rh2
• Title of publication: Rhodium(0) Metalloradicals in Binuclear C-H Activation
• Authors of publication: Florian F. Puschmann; Hansjörg Grützmacher; Bas de Bruin
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2010
• Journal volume: 132
• Pages of publication: 73 - 75
• a: 12.245 ± 0.003 Å
• b: 14.106 ± 0.003 Å
• c: 15.104 ± 0.003 Å
• α: 63.58 ± 0.03°
• β: 78.33 ± 0.03°
• γ: 66.59 ± 0.03°
• Cell volume: 2143.1 ± 1.1 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0493
• Residual factor for significantly intense reflections: 0.0392
• Weighted residual factors for significantly intense reflections: 0.0814
• Weighted residual factors for all reflections included in the refinement: 0.0857
• Goodness-of-fit parameter for all reflections included in the refinement: 0.99
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No