Information card for entry 4102023

Structure parameters

• Formula: C36 H50 N2 S Si
• Calculated formula: C36 H50 N2 S Si
• Title of publication: Steering S-H and N-H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)\ρightarrowNi(CO)3Complex
• Authors of publication: Antje Meltzer; Shigeyoshi Inoue; Carsten Präsang; Matthias Driess
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2010
• Journal volume: 132
• Pages of publication: 3038 - 3046
• a: 13.4204 ± 0.0005 Å
• b: 16.5796 ± 0.0006 Å
• c: 15.4482 ± 0.0006 Å
• α: 90°
• β: 92.315 ± 0.004°
• γ: 90°
• Cell volume: 3434.5 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0833
• Residual factor for significantly intense reflections: 0.0555
• Weighted residual factors for significantly intense reflections: 0.114
• Weighted residual factors for all reflections included in the refinement: 0.1243
• Goodness-of-fit parameter for all reflections included in the refinement: 1.083
• Diffraction radiation wavelength: 0.71073 Å
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No