Crystallography Open Database

Information card for entry 4103061

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Coordinates	4103061.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C51 H66 N3 O P Si
Calculated formula	C51 H66 N3 O P Si
Title of publication	Diastereoselective Synthesis of Bulky, Strongly Nucleophilic, and Configurationally Stable P-Stereogenic Tricyclic Phosphines
Authors of publication	David Gau; Ricardo Rodriguez; Tsuyoshi Kato; Nathalie Saffon-Merceron; Antoine Baceiredo
Journal of publication	Journal of the American Chemical Society
Year of publication	2010
Journal volume	132
Pages of publication	12841 - 12843
a	11.759 ± 0.0003 Å
b	12.459 ± 0.0002 Å
c	18.486 ± 0.0003 Å
α	72.49 ± 0.001°
β	85.614 ± 0.001°
γ	62.576 ± 0.001°
Cell volume	2286.38 ± 0.08 Å³
Cell temperature	193 ± 2 K
Ambient diffraction temperature	193 ± 2 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0726
Residual factor for significantly intense reflections	0.0541
Weighted residual factors for significantly intense reflections	0.1403
Weighted residual factors for all reflections included in the refinement	0.154
Goodness-of-fit parameter for all reflections included in the refinement	1.05
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

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