Information card for entry 4103246

Structure parameters

• Formula: C47 H108 Cl2 N2 Si12 Zn
• Calculated formula: C47 H108 Cl2 N2 Si12 Zn
• SMILES: C([Si](C([Si](C)(C)C)[Si](C)(C)C)(C(C)C)[Si](=C1N(C(=C(C)N1C)C)C)[Si]([Si](C([Si](C)(C)C)[Si](C)(C)C)(C([Si](C)(C)C)[Si](C)(C)C)C(C)C)=[Zn](Cl)Cl)([Si](C)(C)C)[Si](C)(C)C.c1ccccc1
• Title of publication: An N-Heterocyclic Carbene-Disilyne Complex and Its Reactivity toward ZnCl2
• Authors of publication: Torahiko Yamaguchi; Akira Sekiguchi; Matthias Driess
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2010
• Journal volume: 132
• Pages of publication: 14061 - 14063
• a: 10.3809 ± 0.0012 Å
• b: 16.1779 ± 0.0019 Å
• c: 21.481 ± 0.003 Å
• α: 93.502 ± 0.002°
• β: 90.604 ± 0.002°
• γ: 107.516 ± 0.002°
• Cell volume: 3432.3 ± 0.7 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.077
• Residual factor for significantly intense reflections: 0.0479
• Weighted residual factors for significantly intense reflections: 0.1137
• Weighted residual factors for all reflections included in the refinement: 0.127
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No