Information card for entry 4104149

Structure parameters

• Formula: C34 H60 Os P Sn
• Calculated formula: C34 H61 Os P Sn
• SMILES: [OsH]1234(=[SnH]c5c(cc(cc5C(C)C)C(C)C)C(C)C)([P](C(C)C)(C(C)C)C(C)C)[c]5([c]1([c]3([c]2([c]45C)C)C)C)C
• Title of publication: A Hydrogen-Substituted Osmium Stannylene Complex: Isomerization to a Metallostannylene Complex via an Unusual α-Hydrogen Migration from Tin to Osmium
• Authors of publication: Paul G. Hayes; Christopher W. Gribble; Rory Waterman; T. Don Tilley
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 4606 - 4607
• a: 9.0526 ± 0.001 Å
• b: 14.0417 ± 0.0016 Å
• c: 28.238 ± 0.003 Å
• α: 90°
• β: 99.027 ± 0.002°
• γ: 90°
• Cell volume: 3545 ± 0.7 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0704
• Residual factor for significantly intense reflections: 0.0481
• Weighted residual factors for significantly intense reflections: 0.1081
• Weighted residual factors for all reflections included in the refinement: 0.1165
• Goodness-of-fit parameter for all reflections included in the refinement: 0.924
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No