Information card for entry 4104349

Structure parameters

• Common name: (IPr)Au[eta2-(CH3)2C=C(CH3)2]+ SbF6-
• Formula: C35 H52 Au Cl4 F6 N2 Sb
• Calculated formula: C35 H52 Au Cl4 F6 N2 Sb
• Title of publication: Syntheses, X-ray Crystal Structures, and Solution Behavior of Monomeric, Cationic, Two-Coordinate Gold(I) π-Alkene Complexes
• Authors of publication: Timothy J. Brown; Marina G. Dickens; Ross A. Widenhoefer
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 6350 - 6351
• a: 16.9803 ± 0.0005 Å
• b: 12.2366 ± 0.0004 Å
• c: 21.7326 ± 0.0006 Å
• α: 90°
• β: 110.479 ± 0.002°
• γ: 90°
• Cell volume: 4230.2 ± 0.2 ų
• Cell temperature: 110 ± 1 K
• Ambient diffraction temperature: 110 ± 1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0705
• Residual factor for significantly intense reflections: 0.0391
• Weighted residual factors for significantly intense reflections: 0.0765
• Weighted residual factors for all reflections included in the refinement: 0.0838
• Goodness-of-fit parameter for all reflections included in the refinement: 1.073
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No