Information card for entry 4104462

Structure parameters

• Formula: C29 H37 I N4 Pt2 Si
• Calculated formula: C29 H37 I N4 Pt2 Si
• SMILES: [Pt]1([Pt]2(I)([n]3ccccc3c3[n]2cccc3)(C)C)([n]2ccccc2c2[n]1cccc2)(C#C[Si](C)(C)C)(C)C
• Title of publication: Binuclear Intermediates in Oxidation Reactions: [(Me3SiC\τbC)Me2(bipy)Pt-PtMe2(bipy)]+ in the Oxidation of PtIIMe2(bipy) (bipy = 2,2'-Bipyridine) by IPh(C\τbCSiMe3)(OTf) (OTf = Triflate)
• Authors of publication: Allan J. Canty; Michael G. Gardiner; Roderick C. Jones; Thomas Rodemann; Manab Sharma
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 7236 - 7237
• a: 8.25 ± 0.0009 Å
• b: 9.685 ± 0.0009 Å
• c: 21.036 ± 0.0013 Å
• α: 96.373 ± 0.005°
• β: 98.346 ± 0.006°
• γ: 101.48 ± 0.003°
• Cell volume: 1612.7 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0301
• Residual factor for significantly intense reflections: 0.0296
• Weighted residual factors for significantly intense reflections: 0.0787
• Weighted residual factors for all reflections included in the refinement: 0.0791
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.77487 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No