Information card for entry 4104673

Structure parameters

• Chemical name: N-pyridine-tris(triphenylsiloxy)-molybdenum-nitride
• Formula: C66 H58 Mo N2 O3 Si3
• Calculated formula: C66 H50 Mo N2 O3 Si3
• Title of publication: Molybdenum Nitride Complexes with Ph3SiO Ligands Are Exceedingly Practical and Tolerant Precatalysts for Alkyne Metathesis and Efficient Nitrogen Transfer Agents
• Authors of publication: Martin Bindl; Robert Stade; Eike K. Heilmann; Alexandre Picot; Richard Goddard; Alois Fürstner
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 9468 - 9470
• a: 13.0697 ± 0.0002 Å
• b: 13.5755 ± 0.0003 Å
• c: 18.2169 ± 0.0003 Å
• α: 87.206 ± 0.001°
• β: 77.527 ± 0.001°
• γ: 64.003 ± 0.001°
• Cell volume: 2832.69 ± 0.09 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0784
• Residual factor for significantly intense reflections: 0.0586
• Weighted residual factors for significantly intense reflections: 0.1433
• Weighted residual factors for all reflections included in the refinement: 0.1565
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No