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Information card for entry 4104726
Preview
Coordinates | 4104726.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | (CO)2Rh(Si3C2) |
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Formula | C35 H73 O2 Rh Si6 |
Calculated formula | C35 H73 O2 Rh Si6 |
SMILES | [Rh]1234([Si]5(=[Si]1([Si]2([C]3(=[C]45CC)CC)[Si](C)(C(C)(C)C)C(C)(C)C)[Si](C)(C(C)(C)C)C(C)(C)C)[Si](C)(C(C)(C)C)C(C)(C)C)(C#[O])C#[O] |
Title of publication | η5-1,2,3-Trisilacyclopentadienyl - A Ligand for Transition Metal Complexes: Rhodium Half-Sandwich and Ruthenium Sandwich |
Authors of publication | Hiroyuki Yasuda; Vladimir Ya. Lee; Akira Sekiguchi |
Journal of publication | Journal of the American Chemical Society |
Year of publication | 2009 |
Journal volume | 131 |
Pages of publication | 9902 - 9903 |
a | 9.265 ± 0.0002 Å |
b | 13.355 ± 0.0006 Å |
c | 18.832 ± 0.0008 Å |
α | 98.802 ± 0.002° |
β | 98.343 ± 0.002° |
γ | 99.888 ± 0.003° |
Cell volume | 2233.09 ± 0.15 Å3 |
Cell temperature | 150 ± 0.1 K |
Ambient diffraction temperature | 150 ± 0.1 K |
Number of distinct elements | 5 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0436 |
Residual factor for significantly intense reflections | 0.0362 |
Weighted residual factors for significantly intense reflections | 0.0945 |
Weighted residual factors for all reflections included in the refinement | 0.0979 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.025 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4104726.html
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Users of the data should acknowledge the original authors of the
structural data.