Information card for entry 4104870

Structure parameters

• Formula: C21 H35 N O4 S
• Calculated formula: C21 H35 N O4 S
• SMILES: S1(=O)(=O)N(C(=O)[C@H](C)[C@@](O)([C@H](CC)C)CC=C)[C@H]2[C@@]3(CC[C@H](C2)C3(C)C)C1
• Title of publication: Stereoselective Synthesis of α-Alkyl-β-keto Imides via Asymmetric Redox C-C Bond Formation between α-Alkyl-α-diazocarbonyl Compounds and Aldehydes
• Authors of publication: Takuya Hashimoto; Hisashi Miyamoto; Yuki Naganawa; Keiji Maruoka
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2009
• Journal volume: 131
• Pages of publication: 11280 - 11281
• a: 11.581 ± 0.0002 Å
• b: 15.0562 ± 0.0003 Å
• c: 24.723 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4310.85 ± 0.14 ų
• Cell temperature: 123.1 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for significantly intense reflections: 0.038
• Weighted residual factors for all reflections included in the refinement: 0.0956
• Goodness-of-fit parameter for all reflections included in the refinement: 1.159
• Diffraction radiation wavelength: 1.54187 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No