Crystallography Open Database

Information card for entry 4105608

Preview

Coordinates	4105608.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C33 H50 Cl2 F6 N4 P Rh
Calculated formula	C33 H50 Cl2 F6 N4 P Rh
Title of publication	Hydrosilylation with Biscarbene Rh(I) Complexes: Experimental Evidence for a Silylene-Based Mechanism
Authors of publication	Peter Gigler; Bettina Bechlars; Wolfgang A. Herrmann; Fritz E. Kühn
Journal of publication	Journal of the American Chemical Society
Year of publication	2011
Journal volume	133
Pages of publication	1589 - 1596
a	11.6445 ± 0.0004 Å
b	12.6184 ± 0.0004 Å
c	12.7872 ± 0.0004 Å
α	90°
β	97.897 ± 0.002°
γ	90°
Cell volume	1861.07 ± 0.11 Å³
Cell temperature	173 ± 2 K
Ambient diffraction temperature	173 ± 2 K
Number of distinct elements	7
Space group number	4
Hermann-Mauguin space group symbol	P 1 21 1
Hall space group symbol	P 2yb
Residual factor for all reflections	0.0336
Residual factor for significantly intense reflections	0.0295
Weighted residual factors for significantly intense reflections	0.0691
Weighted residual factors for all reflections included in the refinement	0.0731
Goodness-of-fit parameter for all reflections included in the refinement	1.092
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

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