Information card for entry 4106476

Structure parameters

• Formula: C20 H48 Cl4 Li O8 U
• Calculated formula: C20 H48 Cl4 Li O8 U
• SMILES: [U](Cl)(Cl)(Cl)(Cl)(OC(C)(C)C)OC(C)(C)C.[O]1(CC[O](C)[Li]231([O](CC[O]2C)C)[O](C)CC[O]3C)C
• Title of publication: High-Valent Uranium Alkyls: Evidence for the Formation of UVI(CH2SiMe3)6
• Authors of publication: Skye Fortier; Justin R. Walensky; Guang Wu; Trevor W. Hayton
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2011
• Journal volume: 133
• Pages of publication: 11732 - 11743
• a: 11.0534 ± 0.0016 Å
• b: 15.79 ± 0.002 Å
• c: 19.038 ± 0.003 Å
• α: 90°
• β: 92.248 ± 0.002°
• γ: 90°
• Cell volume: 3320.2 ± 0.8 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0503
• Residual factor for significantly intense reflections: 0.035
• Weighted residual factors for significantly intense reflections: 0.0856
• Weighted residual factors for all reflections included in the refinement: 0.0922
• Goodness-of-fit parameter for all reflections included in the refinement: 1.001
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No