Information card for entry 4108666

Structure parameters

• Formula: C42 H67 F6 N P2 Pt
• Calculated formula: C42 H67 F6 N P2 Pt
• Title of publication: Competing C-F Activation Pathways in the Reaction of Pt(0) with Fluoropyridines: Phosphine-Assistance versus Oxidative Addition
• Authors of publication: Ainara Nova; Stefan Erhardt; Naseralla A. Jasim; Robin N. Perutz; Stuart A. Macgregor; John E. McGrady; Adrian C. Whitwood
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2008
• Journal volume: 130
• Pages of publication: 15499 - 15511
• a: 11.9912 ± 0.0002 Å
• b: 18.4427 ± 0.0002 Å
• c: 22.0438 ± 0.0002 Å
• α: 113.445 ± 0.001°
• β: 105.634 ± 0.001°
• γ: 90.072 ± 0.001°
• Cell volume: 4274.46 ± 0.1 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0418
• Residual factor for significantly intense reflections: 0.0352
• Weighted residual factors for significantly intense reflections: 0.0749
• Weighted residual factors for all reflections included in the refinement: 0.0778
• Goodness-of-fit parameter for all reflections included in the refinement: 1.094
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No