Information card for entry 4109094

Structure parameters

• Formula: C25 H42 O P Rh Si
• Calculated formula: C25 H42 O P Rh Si
• Title of publication: Scope and Mechanism of the Intermolecular Addition of Aromatic Aldehydes to Olefins Catalyzed by Rh(I) Olefin Complexes
• Authors of publication: Amy H. Roy; Christian P. Lenges; Maurice Brookhart
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2007
• Journal volume: 129
• Pages of publication: 2082 - 2093
• a: 17.5945 ± 0.0008 Å
• b: 8.6401 ± 0.0004 Å
• c: 17.4677 ± 0.0008 Å
• α: 90°
• β: 94.092 ± 0.001°
• γ: 90°
• Cell volume: 2648.6 ± 0.2 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.021
• Residual factor for significantly intense reflections: 0.017
• Weighted residual factors for all reflections: 0.022
• Weighted residual factors for significantly intense reflections: 0.022
• Goodness-of-fit parameter for all reflections included in the refinement: 1.33
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MolybdenumKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No