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Information card for entry 4109097
Preview
Coordinates | 4109097.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C78 H76 Cl6 O2 P3 Rh3 |
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Calculated formula | C78 H76 Cl6 O2 P3 Rh3 |
SMILES | [Rh]123([O]4[Rh]56([OH]1[Rh]417[P]([C@H]4[C@H]8[CH]1=[C]7([C@@H]4CC8)c1ccccc1)(c1ccccc1)c1ccccc1)[P]([C@H]1[C@H]4[CH]5=[C]6([C@@H]1CC4)c1ccccc1)(c1ccccc1)c1ccccc1)[P]([C@H]1[C@H]4[CH]2=[C]3([C@@H]1CC4)c1ccccc1)(c1ccccc1)c1ccccc1.ClCCl.ClCCl.ClCCl |
Title of publication | Chiral Phosphine-Olefin Ligands in the Rhodium-Catalyzed Asymmetric 1,4-Addition Reactions |
Authors of publication | Wei-Liang Duan; Hiroshi Iwamura; Ryo Shintani; Tamio Hayashi |
Journal of publication | Journal of the American Chemical Society |
Year of publication | 2007 |
Journal volume | 129 |
Pages of publication | 2130 - 2138 |
a | 15.182 ± 0.001 Å |
b | 19.779 ± 0.002 Å |
c | 23.308 ± 0.002 Å |
α | 90° |
β | 90° |
γ | 90° |
Cell volume | 6999 ± 1 Å3 |
Cell temperature | 296.1 K |
Number of distinct elements | 6 |
Space group number | 19 |
Hermann-Mauguin space group symbol | P 21 21 21 |
Hall space group symbol | P 2ac 2ab |
Residual factor for significantly intense reflections | 0.029 |
Weighted residual factors for all reflections included in the refinement | 0.036 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.01 |
Diffraction radiation wavelength | 0.7107 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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