Information card for entry 4109148

Structure parameters

• Formula: Ge2 H74 Na16 Np2 O109 W18
• Calculated formula: Ge2 Na16 Np2 O109 W18
• SMILES: O=[Np]1234(=O)[O]=[W]567(=O)[O]8[W]9(=[O]1)(O7)(=O)O[W]17(=O)(=O)[O]%10[W]%11%12(O7)(=O)O[W]7%13(O1)(=O)O[W]1%14%15(=O)O[W]%16(O6)(=O)(=O)[O]([Ge]8%10[O]7%14[W](=O)(O1)(O5)(O9)O%13)[W]1(O%15)(O%16)(=O)=[O][Np]5(=O)(=O)([O]=%12)([O]1%11)[O]=[W]167(=O)[O]8[W]9(=[O]5)(O1)(=O)O[W]15(=O)(=O)[O]%10[W]%11(=[O]2)(O5)(=O)[O]4[W]24(=[O]3)(=O)[O]3[W](=O)(O6)(O4)(=O)O[W]45(O2)(=O)O[W]2(=O)(O1)(O%11)[O]4([Ge]38%10)[W](=O)(O5)(O7)(O9)O2.[Na+].O.O.O.O.O.[Na+].[Na+].O.O.O.O.O.[Na+].O.O.[Na+].O.[Na+].O.O.O.[Na+].O.[Na+].O.O.O.[Na+].[Na+].O.O.O.O.O.[Na+].O.[Na+].O.O.O.[Na+].O.[Na+].O.O.[Na+].O.O.[Na+].O.O.O
• Title of publication: Luminescence from Neptunyl(VI) Species in Solution
• Authors of publication: Catherine Talbot-Eeckelaers; Simon J. A. Pope; Amanda J. Hynes; Roy Copping; Chris J. Jones; Robin J. Taylor; Stephen Faulkner; Daniel Sykes; Francis R. Livens; Iain May
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2007
• Journal volume: 129
• Pages of publication: 2442 - 2443
• a: 13.352 ± 0.003 Å
• b: 13.409 ± 0.003 Å
• c: 16.143 ± 0.003 Å
• α: 85.04 ± 0.03°
• β: 73.27 ± 0.03°
• γ: 64.51 ± 0.03°
• Cell volume: 2496.1 ± 1.2 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1291
• Residual factor for significantly intense reflections: 0.0998
• Weighted residual factors for significantly intense reflections: 0.2391
• Weighted residual factors for all reflections included in the refinement: 0.2552
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No