Information card for entry 4109602

Structure parameters

• Formula: C142 H176 F10 P4 Pt2
• Calculated formula: C142 H176 F10 P4 Pt2
• SMILES: C1#CC#CC#CC#C[Pt]2([P](CCCCCCCCCCCCCC[P](c3ccc(cc3)C(C)(C)C)(c3ccc(cc3)C(C)(C)C)[Pt]1([P](CCCCCCCCCCCCCC[P]2(c1ccc(cc1)C(C)(C)C)c1ccc(cc1)C(C)(C)C)(c1ccc(cc1)C(C)(C)C)c1ccc(cc1)C(C)(C)C)c1c(c(c(c(c1F)F)F)F)F)(c1ccc(cc1)C(C)(C)C)c1ccc(cc1)C(C)(C)C)c1c(c(c(c(c1F)F)F)F)F.Cc1ccccc1.Cc1ccccc1
• Title of publication: sp Carbon Chains Surrounded by sp3 Carbon Double Helices: Coordination-Driven Self-Assembly of Wirelike Pt(C\τbC)nPt Moieties That Are Spanned by Two P(CH2)mP Linkages
• Authors of publication: Jürgen Stahl; Wolfgang Mohr; Laura de Quadras; Thomas B. Peters; James C. Bohling; José Miguel Martín-Alvarez; Gareth R. Owen; Frank Hampel; John A. Gladysz
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2007
• Journal volume: 129
• Pages of publication: 8282 - 8295
• a: 15.882 ± 0.003 Å
• b: 30.726 ± 0.006 Å
• c: 13.287 ± 0.003 Å
• α: 90°
• β: 96.31 ± 0.03°
• γ: 90°
• Cell volume: 6445 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0971
• Residual factor for significantly intense reflections: 0.0498
• Weighted residual factors for significantly intense reflections: 0.1032
• Weighted residual factors for all reflections included in the refinement: 0.1231
• Goodness-of-fit parameter for all reflections included in the refinement: 0.951
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No