Information card for entry 4109651

Structure parameters

• Formula: C35 H65 F3 N3 O3 Os P2 S Si2
• Calculated formula: C35 H65 F3 N3 O3 Os P2 S Si2
• SMILES: [Os]12([P](C[Si]([NH]2[Si](C)(C)C[P]1(C(C)(C)C)C(C)(C)C)(C)C)(C(C)(C)C)C(C)(C)C)[N]#N.S(=O)(=O)([O-])C(F)(F)F.c1ccccc1.c1ccccc1
• Title of publication: Facile Hydrogenation of N2O by an Operationally Unsaturated Osmium Polyhydride
• Authors of publication: Joo-Ho Lee; Maren Pink; John Tomaszewski; Hongjun Fan; Kenneth G. Caulton
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2007
• Journal volume: 129
• Pages of publication: 8706 - 8707
• a: 11.545 ± 0.003 Å
• b: 29.626 ± 0.007 Å
• c: 12.883 ± 0.003 Å
• α: 90°
• β: 94.026 ± 0.007°
• γ: 90°
• Cell volume: 4395.5 ± 1.9 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.099
• Residual factor for significantly intense reflections: 0.0593
• Weighted residual factors for significantly intense reflections: 0.1559
• Weighted residual factors for all reflections included in the refinement: 0.2142
• Goodness-of-fit parameter for all reflections included in the refinement: 1.161
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No