Information card for entry 4109666

Structure parameters

• Formula: C43 H67 B F4 N O1.5 Os P2
• Calculated formula: C43 H67 B F4 N O1.5 Os P2
• Title of publication: Sequential and Selective Hydrogenation of the Cα-Cβ and M-Cα Double Bonds of an Allenylidene Ligand Coordinated to Osmium: New Reaction Patterns between an Allenylidene Complex and Alcohols
• Authors of publication: Tamara Bolaño; Ricardo Castarlenas; Miguel A. Esteruelas; Enrique Oñate
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2007
• Journal volume: 129
• Pages of publication: 8850 - 8859
• a: 14.6813 ± 0.0019 Å
• b: 13.9813 ± 0.0017 Å
• c: 21.656 ± 0.003 Å
• α: 90°
• β: 90.816 ± 0.002°
• γ: 90°
• Cell volume: 4444.7 ± 1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0748
• Residual factor for significantly intense reflections: 0.0453
• Weighted residual factors for significantly intense reflections: 0.0684
• Weighted residual factors for all reflections included in the refinement: 0.0753
• Goodness-of-fit parameter for all reflections included in the refinement: 0.884
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No