Information card for entry 4110575

Structure parameters

• Common name: [Ag4(bppn)4][SbF6]4 . CH3NO2
• Formula: C60 H52 Ag4 F24 N20 O8 Sb4
• Calculated formula: C60 H52 Ag4 F24 N20 O8 Sb4
• SMILES: [F-][Sb](F)(F)(F)(F)F.F[Sb](F)(F)(F)(F)[F-].[n]12[Ag]34[n]5[n]6c(ccc5c2cccc1)c1[n]([Ag]26[n]5[n]6[Ag]7([n]8ccccc8c8ccc9[n]([n]78)[Ag]7([n]8c(ccc(c%10cccc[n]3%10)[n]48)c3[n]7cccc3)[n]3c9cccc3)[n]3ccccc3c6ccc5c3[n]2cccc3)cccc1.CN(=O)=O.CN(=O)=O.[F-][Sb](F)(F)(F)(F)F.F[Sb](F)(F)(F)(F)[F-].CN(=O)=O.CN(=O)=O
• Title of publication: Anion-π Interactions as Controlling Elements in Self-Assembly Reactions of Ag(I) Complexes with π-Acidic Aromatic Rings
• Authors of publication: Brandi L. Schottel; Helen T. Chifotides; Mikhail Shatruk; Abdellatif Chouai; Lisa M. Pérez; John Bacsa; Kim R. Dunbar
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2006
• Journal volume: 128
• Pages of publication: 5895 - 5912
• a: 23.595 ± 0.005 Å
• b: 14.62 ± 0.003 Å
• c: 25.322 ± 0.005 Å
• α: 90°
• β: 116.38 ± 0.03°
• γ: 90°
• Cell volume: 7825 ± 3 ų
• Cell temperature: 111 ± 2 K
• Ambient diffraction temperature: 111 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0609
• Residual factor for significantly intense reflections: 0.0489
• Weighted residual factors for significantly intense reflections: 0.1149
• Weighted residual factors for all reflections included in the refinement: 0.1211
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No