Information card for entry 4111736

Structure parameters

• Formula: C34 H56 Li2 N2 O2 Si2
• Calculated formula: C34 H56 Li2 N2 O2 Si2
• SMILES: C[Si]1(c2ccccc2)C[N]2(CCCCC2)[Li]([Si]2(C)(c3ccccc3)[Li]1([N]1(C2)CCCCC1)[O]1CCCC1)[O]1CCCC1
• Title of publication: Selective Si-C Bond Cleavage as Synthetic Entry to a Functionalized Lithiosilane
• Authors of publication: Carsten Strohmann; Daniel Schildbach; Dominik Auer
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2005
• Journal volume: 127
• Pages of publication: 7968 - 7969
• a: 19.777 ± 0.004 Å
• b: 10.4 ± 0.002 Å
• c: 35.503 ± 0.007 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 7302 ± 2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 33
• Hermann-Mauguin space group symbol: P n a 21
• Hall space group symbol: P 2c -2n
• Residual factor for all reflections: 0.1163
• Residual factor for significantly intense reflections: 0.0801
• Weighted residual factors for significantly intense reflections: 0.1663
• Weighted residual factors for all reflections included in the refinement: 0.1829
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No