Information card for entry 4112323

Structure parameters

• Formula: C84 H72 F2 P4 Rh2
• Calculated formula: C78 H66 F2 P4 Rh2
• Title of publication: The Fluoro Analogue of Wilkinson's Catalyst and Unexpected Ph-Cl Activation
• Authors of publication: Vladimir V. Grushin; William J. Marshall
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2004
• Journal volume: 126
• Pages of publication: 3068 - 3069
• a: 21.483 ± 0.003 Å
• b: 18.103 ± 0.002 Å
• c: 17.662 ± 0.002 Å
• α: 90°
• β: 91.646 ± 0.002°
• γ: 90°
• Cell volume: 6866 ± 1.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0778
• Residual factor for significantly intense reflections: 0.0642
• Weighted residual factors for significantly intense reflections: 0.1816
• Weighted residual factors for all reflections included in the refinement: 0.191
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No