Information card for entry 4113424

Structure parameters

• Common name: VOCl3 + carbene
• Formula: C21 H24 Cl3 N2 O V
• Calculated formula: C21 H24 Cl3 N2 O V
• Title of publication: A Highly Stable N-Heterocyclic Carbene Complex of Trichloro-oxo-vanadium(V) Displaying Novel Cl-Ccarbene Bonding Interactions
• Authors of publication: Colin D. Abernethy; Gareth M. Codd; Mark D. Spicer; Michelle K. Taylor
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 1128 - 1129
• a: 7.8641 ± 0.0002 Å
• b: 8.2857 ± 0.0002 Å
• c: 18.2282 ± 0.0005 Å
• α: 102.388°
• β: 91.132 ± 0.001°
• γ: 108.175°
• Cell volume: 1097.39 ± 0.05 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0557
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0795
• Weighted residual factors for all reflections included in the refinement: 0.0873
• Goodness-of-fit parameter for all reflections included in the refinement: 1.003
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No