Crystallography Open Database

Information card for entry 4113495

Preview

Coordinates	4113495.cif
Original paper (by DOI)	HTML

Structure parameters

Chemical name	tetrakis(N,N'-diphenylformamidinato)divanadium(II,II)
Formula	C52 H44 N8 V2
Calculated formula	C52 H44 N8 V2
Title of publication	A Highly Reduced V23+ Unit with a Metal-Metal Bond Order of 3.5
Authors of publication	F. Albert Cotton; Elizabeth A. Hillard; Carlos A. Murillo
Journal of publication	Journal of the American Chemical Society
Year of publication	2003
Journal volume	125
Pages of publication	2026 - 2027
a	17.874 ± 0.0014 Å
b	10.3011 ± 0.0008 Å
c	24.4161 ± 0.0019 Å
α	90°
β	102.156 ± 0.002°
γ	90°
Cell volume	4394.7 ± 0.6 Å³
Cell temperature	213 ± 2 K
Ambient diffraction temperature	213 ± 2 K
Number of distinct elements	4
Space group number	13
Hermann-Mauguin space group symbol	P 1 2/n 1
Hall space group symbol	-P 2yac
Residual factor for all reflections	0.0892
Residual factor for significantly intense reflections	0.0568
Weighted residual factors for significantly intense reflections	0.1361
Weighted residual factors for all reflections included in the refinement	0.1533
Goodness-of-fit parameter for all reflections included in the refinement	1.02
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	No
Has F_obs	No

For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4113495.html