Information card for entry 4113862

Structure parameters

• Formula: C18 H54 P4 Ru Si2
• Calculated formula: C18 H54 P4 Ru Si2
• Title of publication: Synthesis and Reactivity of Silyl Ruthenium Complexes: The Importance of Trans Effects in C-H Activation, Si-C Bond Formation, and Dehydrogenative Coupling of Silanes
• Authors of publication: Vladimir K. Dioumaev; Leo J. Procopio; Patrick J. Carroll; Donald H. Berry
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2003
• Journal volume: 125
• Pages of publication: 8043 - 8058
• a: 12.3876 ± 0.0001 Å
• b: 23.6973 ± 0.0003 Å
• c: 10.2102 ± 0.0001 Å
• α: 90°
• β: 97.801 ± 0.001°
• γ: 90°
• Cell volume: 2969.49 ± 0.05 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0512
• Residual factor for significantly intense reflections: 0.0448
• Weighted residual factors for all reflections: 0.1035
• Weighted residual factors for significantly intense reflections: 0.1004
• Goodness-of-fit parameter for all reflections: 1.182
• Goodness-of-fit parameter for significantly intense reflections: 1.194
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No