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Information card for entry 4113977
Preview
Coordinates | 4113977.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C15 H45 P3 Ru Si2 |
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Calculated formula | C15 H45 P3 Ru Si2 |
SMILES | [RuH]1([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[H][Si](C)(C)CC[Si]1(C)C |
Title of publication | Structure and Reactivity of Bis(silyl) Dihydride Complexes (PMe3)3Ru(SiR3)2(H)2: Model Compounds and Real Intermediates in a Dehydrogenative C-Si Bond Forming Reaction |
Authors of publication | Vladimir K. Dioumaev; Bok R. Yoo; Leo J. Procopio; Patrick J. Carroll; Donald H. Berry |
Journal of publication | Journal of the American Chemical Society |
Year of publication | 2003 |
Journal volume | 125 |
Pages of publication | 8936 - 8948 |
a | 35.9187 ± 0.0005 Å |
b | 9.321 ± 0.0001 Å |
c | 16.1099 ± 0.0001 Å |
α | 90° |
β | 114.123 ± 0.001° |
γ | 90° |
Cell volume | 4922.55 ± 0.1 Å3 |
Cell temperature | 200 ± 2 K |
Ambient diffraction temperature | 200 ± 2 K |
Number of distinct elements | 5 |
Space group number | 15 |
Hermann-Mauguin space group symbol | C 1 2/c 1 |
Hall space group symbol | -C 2yc |
Residual factor for all reflections | 0.0507 |
Residual factor for significantly intense reflections | 0.0445 |
Weighted residual factors for all reflections | 0.1107 |
Weighted residual factors for significantly intense reflections | 0.1065 |
Goodness-of-fit parameter for all reflections | 1.103 |
Goodness-of-fit parameter for significantly intense reflections | 1.113 |
Diffraction radiation wavelength | 0.71069 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/4113977.html
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