Information card for entry 4114586

Structure parameters

• Formula: C28 H47 F6 N2 P Ru2
• Calculated formula: C28 H47 F6 N2 P Ru2
• SMILES: [Ru]123456([N]7(C(C)C)[Ru]89%10%11([N]1(=[C]27C)C(C)C)[c]1([c]%10([c]%11([c]8([c]91C)C)C)C)C)[c]1([c]3([c]6([c]5([c]41C)C)C)C)C.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Novel Coordinatively Unsaturated Bimetallic Complexes, [(η5-C5Me5)Ru(μ2-iPrNC(Me)NiPr)Ru(η5-C5Me5)]+: A Bridging Amidinate Ligand Perpendicular to the Metal-Metal Axis Effectively Stabilizes the Highly Reactive Cationic Diruthenium Species
• Authors of publication: Hideo Kondo; Kouki Matsubara; Hideo Nagashima
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 534 - 535
• a: 31.5792 ± 0.0015 Å
• b: 15.1007 ± 0.0005 Å
• c: 14.4272 ± 0.0007 Å
• α: 90°
• β: 110.971 ± 0.001°
• γ: 90°
• Cell volume: 6424.2 ± 0.5 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0579
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for significantly intense reflections: 0.0949
• Weighted residual factors for all reflections included in the refinement: 0.1039
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No