Information card for entry 4114703

Structure parameters

• Common name: tetrakis(anisylformamidinato)-bis(oxo)dimolybdenum(IV)
• Chemical name: trans-bis-η^2^-(N,N'-di-(p-anisylformamidinato) -bis-μ~2~-oxobis(μ~2~-N,N'-di- (p-anisylformamidinato)dimolybdenum(IV)
• Formula: C62 H64 Cl4 Mo2 N8 O10
• Calculated formula: C62 H64 Cl4 Mo2 N8 O10
• Title of publication: A Pseudo-Jahn-Teller Distortion in an Mo2(μ2-O)2 Ring Having the Shortest MoIV-MoIV Double Bond
• Authors of publication: F. Albert Cotton; Lee M. Daniels; Carlos A. Murillo; J. Garrett Slaton
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 2878 - 2879
• a: 13.2805 ± 0.0007 Å
• b: 10.3291 ± 0.0005 Å
• c: 22.9583 ± 0.0012 Å
• α: 90°
• β: 92.136 ± 0.001°
• γ: 90°
• Cell volume: 3147.1 ± 0.3 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0621
• Residual factor for significantly intense reflections: 0.0453
• Weighted residual factors for significantly intense reflections: 0.1138
• Weighted residual factors for all reflections included in the refinement: 0.1256
• Goodness-of-fit parameter for all reflections included in the refinement: 1.052
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No