Information card for entry 4114739

Structure parameters

• Formula: C42 H73 O2 P3 Pt
• Calculated formula: C42 H73 O2 P3 Pt
• SMILES: [PtH]1([P](C2CCCCC2)(C2CCCCC2)CC[P]1(C1CCCCC1)C1CCCCC1)[P@@](=O)(O[C@H]1[C@@H](CC[C@H](C1)C)C(C)C)c1ccccc1
• Title of publication: Retention of Configuration on the Oxidative Addition of P-H Bond to Platinum (0) Complexes: The First Straightforward Synthesis of Enantiomerically Pure P-Chiral Alkenylphosphinates via Palladium-Catalyzed Stereospecific Hydrophosphinylation of Alkynes
• Authors of publication: Li-Biao Han; Chang-Qiu Zhao; Shun-ya Onozawa; Midori Goto; Masato Tanaka
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 3842 - 3843
• a: 17.455 ± 0.006 Å
• b: 21.777 ± 0.004 Å
• c: 11.484 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4365 ± 2 ų
• Cell temperature: 203.2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for significantly intense reflections: 0.0486
• Weighted residual factors for all reflections included in the refinement: 0.1258
• Goodness-of-fit parameter for all reflections included in the refinement: 1.266
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No