Information card for entry 4115041

Structure parameters

• Chemical name: Tris[di-tert-butyl(methyl)silyl]germanyl
• Formula: C27 H63 Ge Si3
• Calculated formula: C27 H63 Ge Si3
• SMILES: [Ge]([Si](C)(C(C)(C)C)C(C)(C)C)([Si](C)(C(C)(C)C)C(C)(C)C)[Si](C)(C(C)(C)C)C(C)(C)C
• Title of publication: Isolable Silyl and Germyl Radicals Lacking Conjugation with π-Bonds: Synthesis, Characterization, and Reactivity
• Authors of publication: Akira Sekiguchi; Tomohide Fukawa; Masaaki Nakamoto; Vladimir Ya. Lee; Masaaki Ichinohe
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 9865 - 9869
• a: 9.079 ± 0.0002 Å
• b: 31.095 ± 0.0006 Å
• c: 11.816 ± 0.0002 Å
• α: 90°
• β: 93.966 ± 0.001°
• γ: 90°
• Cell volume: 3327.8 ± 0.11 ų
• Cell temperature: 120 K
• Ambient diffraction temperature: 120 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0356
• Residual factor for significantly intense reflections: 0.0334
• Weighted residual factors for significantly intense reflections: 0.0919
• Weighted residual factors for all reflections included in the refinement: 0.0942
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No