Information card for entry 4115347

Structure parameters

• Common name: LCoCl2Li(ether)2
• Chemical name: 2,2,6,6-tetramethyl-3,5-bis(2,6-diisopropylphenylimido)heptyl cobalt(II) bis(mu-chloro)lithium dietherate
• Formula: C43 H71 Cl2 Co Li N2 O2
• Calculated formula: C43 H70.366 Cl2 Co Li N2 O2
• Title of publication: Electronically Unsaturated Three-Coordinate Chloride and Methyl Complexes of Iron, Cobalt, and Nickel
• Authors of publication: Patrick L. Holland; Thomas R. Cundari; Lanyn L. Perez; Nathan A. Eckert; Rene J. Lachicotte
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2002
• Journal volume: 124
• Pages of publication: 14416 - 14424
• a: 10.0886 ± 0.0006 Å
• b: 12.4995 ± 0.0007 Å
• c: 18.3218 ± 0.001 Å
• α: 76.743 ± 0.001°
• β: 80.254 ± 0.001°
• γ: 84.81 ± 0.001°
• Cell volume: 2213.2 ± 0.2 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0642
• Residual factor for significantly intense reflections: 0.0475
• Weighted residual factors for significantly intense reflections: 0.1138
• Weighted residual factors for all reflections included in the refinement: 0.1226
• Goodness-of-fit parameter for all reflections included in the refinement: 1.063
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: mokα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No