Information card for entry 4116198

Structure parameters

• Common name: cesium_bismuthide
• Chemical name: Cs3Bi2
• Formula: Bi2 Cs3
• Calculated formula: Bi2 Cs3
• SMILES: [Bi-][Bi-].[Cs+].[Cs+].[Cs+]
• Title of publication: Synthesis and Characterization of A3Bi2 (A = K, Rb, Cs) with Isolated Diatomic Dianion of Bismuth, [Bi2]2-, and an Extra Delocalized Electron
• Authors of publication: Franck Gascoin; Slavi C. Sevov
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2000
• Journal volume: 122
• Pages of publication: 10251 - 10252
• a: 10.078 ± 0.001 Å
• b: 10.3207 ± 0.0006 Å
• c: 10.145 ± 0.001 Å
• α: 90°
• β: 105.21 ± 0.01°
• γ: 90°
• Cell volume: 1018.24 ± 0.16 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 2
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0693
• Residual factor for significantly intense reflections: 0.0414
• Weighted residual factors for significantly intense reflections: 0.0824
• Weighted residual factors for all reflections included in the refinement: 0.0909
• Goodness-of-fit parameter for all reflections included in the refinement: 1.011
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No