Information card for entry 4116947

Structure parameters

• Chemical name: dihydride [η2-1,2-bis(dimethylsilyl)benzene] bis(tricyclohexyl)phosphine ruthenium(II). benzene
• Formula: C52 H92 P2 Ru Si2
• Calculated formula: C52 H92 P2 Ru Si2
• Title of publication: Synthesis and Characterization of Chelating Bis(silane) Complexes [RuH2{(η2-HSiMe2)2X}(PCy3)2] (X = C6H4, O) Containing Two Ru-(η2-Si-H) Bonds
• Authors of publication: Fabien Delpech; Sylviane Sabo-Etienne; Bruno Chaudret; Jean-Claude Daran
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 1997
• Journal volume: 119
• Pages of publication: 3167 - 3168
• a: 21.033 ± 0.004 Å
• b: 19.714 ± 0.002 Å
• c: 25.336 ± 0.005 Å
• α: 90°
• β: 90.01 ± 0.02°
• γ: 90°
• Cell volume: 10505 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for significantly intense reflections: 0.0446
• Weighted residual factors for significantly intense reflections: 0.0403
• Goodness-of-fit parameter for significantly intense reflections: 1.0706
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No