Information card for entry 4117668

Structure parameters

• Chemical name: U(IV) Ph Ket
• Formula: C63 H86 Li N5 O2 U
• Calculated formula: C63 H77 Li N5 O2 U
• Title of publication: Probing the 5f Orbital Contribution to the Bonding in a U(V) Ketimide Complex
• Authors of publication: Lani A. Seaman; Guang Wu; Norman Edelstein; Wayne W. Lukens; Nicola Magnani; Trevor W. Hayton
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2012
• Journal volume: 134
• Pages of publication: 4931 - 4940
• a: 13.2886 ± 0.0013 Å
• b: 13.9258 ± 0.0014 Å
• c: 18.2372 ± 0.0017 Å
• α: 76.405 ± 0.005°
• β: 77.74 ± 0.005°
• γ: 65.596 ± 0.004°
• Cell volume: 2961.8 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0511
• Residual factor for significantly intense reflections: 0.0452
• Weighted residual factors for significantly intense reflections: 0.1081
• Weighted residual factors for all reflections included in the refinement: 0.1118
• Goodness-of-fit parameter for all reflections included in the refinement: 1.116
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No