Information card for entry 4119874

Structure parameters

• Formula: C24 H20 N2 O6 S
• Calculated formula: C24 H20 N2 O6 S
• SMILES: S(=O)(=O)(N1c2ccccc2[C@@]2(C1=O)[C@@H](c1ccc(OC)cc1)[C@@H]2C)c1ccc(N(=O)=O)cc1
• Title of publication: Highly Stereoselective Olefin Cyclopropanation of Diazooxindoles Catalyzed by a C2-Symmetric Spiroketal Bisphosphine/Au(I) Complex
• Authors of publication: Zhong-Yan Cao; Xiaoming Wang; Chen Tan; Xiao-Li Zhao; Jian Zhou; Kuiling Ding
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2013
• Journal volume: 135
• Pages of publication: 8197 - 8200
• a: 11.2515 ± 0.0005 Å
• b: 12.1303 ± 0.0006 Å
• c: 16.1131 ± 0.0008 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2199.18 ± 0.18 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0511
• Residual factor for significantly intense reflections: 0.0373
• Weighted residual factors for significantly intense reflections: 0.0873
• Weighted residual factors for all reflections included in the refinement: 0.0955
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No