Information card for entry 4120246

Structure parameters

• Formula: C74 H75 B F25 Mn P4 Sn
• Calculated formula: C74 H75 B F25 Mn P4 Sn
• Title of publication: Manganese-Tin Triple Bonds: A New Synthetic Route to the Manganese Stannylidyne Complex Cation trans-[H(dmpe)2Mn\τbSn(C6H3-2,6-Mes2)]+ (dmpe = Me2PCH2CH2PMe2, Mes = 2,4,6-Trimethylphenyl)
• Authors of publication: Alexander C. Filippou; Priyabrata Ghana; Uttam Chakraborty; Gregor Schnakenburg
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2013
• Journal volume: 135
• Pages of publication: 11525 - 11528
• a: 19.4964 ± 0.0003 Å
• b: 15.7107 ± 0.0004 Å
• c: 25.8856 ± 0.0006 Å
• α: 90°
• β: 97.7733 ± 0.0012°
• γ: 90°
• Cell volume: 7856 ± 0.3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0768
• Residual factor for significantly intense reflections: 0.0445
• Weighted residual factors for significantly intense reflections: 0.1166
• Weighted residual factors for all reflections included in the refinement: 0.1281
• Goodness-of-fit parameter for all reflections included in the refinement: 0.998
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No