Information card for entry 4120538

Structure parameters

• Formula: C28 H34 Au2 Cl2 O2 P2
• Calculated formula: C28 H34 Au2 Cl2 O2 P2
• Title of publication: Air-stable gold nanoparticles ligated by secondary phosphine oxides for the chemoselective hydrogenation of aldehydes: crucial role of the ligand.
• Authors of publication: Cano, Israel; Chapman, Andrew M.; Urakawa, Atsushi; van Leeuwen, Piet W. N. M.
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 6
• Pages of publication: 2520 - 2528
• a: 20.686 ± 0.002 Å
• b: 7.1818 ± 0.0008 Å
• c: 21.924 ± 0.003 Å
• α: 90°
• β: 116.008 ± 0.003°
• γ: 90°
• Cell volume: 2927.3 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1036
• Residual factor for significantly intense reflections: 0.088
• Weighted residual factors for significantly intense reflections: 0.1912
• Weighted residual factors for all reflections included in the refinement: 0.197
• Goodness-of-fit parameter for all reflections included in the refinement: 1.273
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No