Information card for entry 4120607

Structure parameters

• Formula: C58 H75 Ge N O2 Si
• Calculated formula: C58 H75 Ge N O2 Si
• SMILES: [Ge](N([Si](C(C)C)(C(C)C)C(C)C)c1c(C(c2ccccc2)c2ccccc2)cc(cc1C(c1ccccc1)c1ccccc1)C(C)C)OCc1ccc(cc1)OC.C(CCC)CC
• Title of publication: Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds.
• Authors of publication: Hadlington, Terrance J.; Hermann, Markus; Frenking, Gernot; Jones, Cameron
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 8
• Pages of publication: 3028
• a: 10.1666 ± 0.0004 Å
• b: 13.8647 ± 0.0006 Å
• c: 19.1051 ± 0.0008 Å
• α: 95.982 ± 0.002°
• β: 103.95 ± 0.002°
• γ: 96.87 ± 0.002°
• Cell volume: 2569.95 ± 0.19 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0627
• Residual factor for significantly intense reflections: 0.0483
• Weighted residual factors for significantly intense reflections: 0.1237
• Weighted residual factors for all reflections included in the refinement: 0.1315
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No