Information card for entry 4120681

Structure parameters

• Formula: C27 H50 Ge O3 Si3 W
• Calculated formula: C27 H50 Ge O3 Si3 W
• SMILES: [W]123456(C#[O])(C#[O])([c]7([c]1([c]2([c]3([c]47C)C)C)C)C)C1(O[GeH]([CH]6=[C]51C)C([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C
• Title of publication: Reactions of a Tungsten-Germylyne Complex with α,β-Unsaturated Ketones: Complete Cleavage of the W≡Ge Bond and Formation of Two Types of η(3)-Germoxyallyl Tungsten Complexes.
• Authors of publication: Fukuda, Tetsuya; Hashimoto, Hisako; Tobita, Hiromi
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 1
• Pages of publication: 80 - 83
• a: 8.9578 ± 0.0007 Å
• b: 9.0925 ± 0.0007 Å
• c: 21.22 ± 0.0017 Å
• α: 81.533 ± 0.006°
• β: 78.365 ± 0.006°
• γ: 76.447 ± 0.005°
• Cell volume: 1636.6 ± 0.2 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0329
• Residual factor for significantly intense reflections: 0.0277
• Weighted residual factors for significantly intense reflections: 0.0583
• Weighted residual factors for all reflections included in the refinement: 0.06
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No