Information card for entry 4121561

Structure parameters

• Formula: Co16 Ge4 H240 Na32 O278 P4 W36
• Calculated formula: Co16 Ge4 Na32.04 O278 P4 W36
• Title of publication: Polyoxometalate-based cobalt-phosphate molecular catalysts for visible light-driven water oxidation.
• Authors of publication: Han, Xin-Bao; Zhang, Zhi-Ming; Zhang, Teng; Li, Yang-Guang; Lin, Wenbin; You, Wansheng; Su, Zhong-Min; Wang, En-Bo
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 14
• Pages of publication: 5359 - 5366
• a: 23.924 ± 0.003 Å
• b: 23.924 ± 0.003 Å
• c: 23.924 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 13693 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 197
• Hermann-Mauguin space group symbol: I 2 3
• Hall space group symbol: I 2 2 3
• Residual factor for all reflections: 0.1558
• Residual factor for significantly intense reflections: 0.1507
• Weighted residual factors for significantly intense reflections: 0.3676
• Weighted residual factors for all reflections included in the refinement: 0.3699
• Goodness-of-fit parameter for all reflections included in the refinement: 1.111
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No