Information card for entry 4121855

Structure parameters

• Formula: Ge6 H186 K22 Na10 O337 W56 Zr24
• Calculated formula: Ge6 K22 Na10 O298 W56 Zr24
• Title of publication: Synergistic Combination of Multi-Zr(IV) Cations and Lacunary Keggin Germanotungstates Leading to a Gigantic Zr24-Cluster-Substituted Polyoxometalate.
• Authors of publication: Huang, Ling; Wang, Sa-Sa; Zhao, Jun-Wei; Cheng, Lin; Yang, Guo-Yu
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 21
• Pages of publication: 7637 - 7642
• a: 17.1764 ± 0.0004 Å
• b: 20.7259 ± 0.0006 Å
• c: 23.1192 ± 0.0005 Å
• α: 67.465 ± 0.002°
• β: 76.759 ± 0.002°
• γ: 73.217 ± 0.002°
• Cell volume: 7212.6 ± 0.3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0635
• Residual factor for significantly intense reflections: 0.0498
• Weighted residual factors for significantly intense reflections: 0.1222
• Weighted residual factors for all reflections included in the refinement: 0.1311
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No