Information card for entry 4121919

Structure parameters

• Formula: C24 H50 Mo P4 Si
• Calculated formula: C24 H50 Mo P4 Si
• SMILES: [MoH]1([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)([P](C)(C)C)[H][SiH](c2ccccc2)(c2ccccc2)[H]1
• Title of publication: Si-H and Si-C Bond Cleavage Reactions of Silane and Phenylsilanes with Mo(PMe3)6: Silyl, Hypervalent Silyl, Silane, and Disilane Complexes.
• Authors of publication: Zuzek, Ashley A.; Parkin, Gerard
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 23
• Pages of publication: 8177 - 8180
• a: 38.441 ± 0.003 Å
• b: 9.6368 ± 0.0008 Å
• c: 16.7191 ± 0.0015 Å
• α: 90°
• β: 99.461 ± 0.001°
• γ: 90°
• Cell volume: 6109.3 ± 0.9 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0716
• Residual factor for significantly intense reflections: 0.0408
• Weighted residual factors for significantly intense reflections: 0.0871
• Weighted residual factors for all reflections included in the refinement: 0.0997
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No