Information card for entry 4122276

Structure parameters

• Formula: C114 H107 Au10 F12 N3 O P10 S4
• Calculated formula: C114 H107 Au10 F12 N3 O P10 S4
• SMILES: c1cccc(c1)[P]1([Au]23[Au]4([Au]5[P](C(=C)[P]([Au]6[Au]78[Au]9([Au]%10%11[Au]%122([Au]([Au]([S]67)[S]3%12)([S]9%10)[S]45)[P](c2ccccc2)(C(=C)[P]%11(c2ccccc2)c2ccccc2)c2ccccc2)[P](C(=C)[P]8(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)[P](C1=C)(c1ccccc1)c1ccccc1)c1ccccc1.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].N#CC.N#CC.C(C)OCC.N#CC
• Title of publication: Addition Reaction-Induced Cluster-to-Cluster Transformation: Controlled Self-Assembly of Luminescent Polynuclear Gold(I) μ3-Sulfido Clusters.
• Authors of publication: Yao, Liao-Yuan; Hau, Franky Ka-Wah; Yam, Vivian Wing-Wah
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 30
• Pages of publication: 10801 - 10806
• a: 17.349 ± 0.004 Å
• b: 19.217 ± 0.004 Å
• c: 19.415 ± 0.004 Å
• α: 87.59 ± 0.03°
• β: 76.89 ± 0.03°
• γ: 72.4 ± 0.03°
• Cell volume: 6007 ± 3 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0936
• Residual factor for significantly intense reflections: 0.0926
• Weighted residual factors for significantly intense reflections: 0.2466
• Weighted residual factors for all reflections included in the refinement: 0.2484
• Goodness-of-fit parameter for all reflections included in the refinement: 1.107
• Diffraction radiation wavelength: 0.7499 Å
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No