Information card for entry 4122361

Structure parameters

• Formula: C26 H32 B Cl Ge N4
• Calculated formula: C26 H32 B Cl Ge N4
• SMILES: [Ge]1(Cl)=C2N(C=CN2[B]([n]2c1n(cc2)C(C)(C)C)(c1ccccc1)c1ccccc1)C(C)(C)C
• Title of publication: Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH](+) Stabilized by a Bis(N-heterocyclic carbene)borate Ligand.
• Authors of publication: Xiong, Yun; Szilvási, Tibor; Yao, Shenglai; Tan, Gengwen; Driess, Matthias
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 32
• Pages of publication: 11300 - 11303
• a: 20.1882 ± 0.0003 Å
• b: 53.1595 ± 0.0011 Å
• c: 10.6226 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 11400.1 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 43
• Hermann-Mauguin space group symbol: F d d 2
• Hall space group symbol: F 2 -2d
• Residual factor for all reflections: 0.0692
• Residual factor for significantly intense reflections: 0.0645
• Weighted residual factors for significantly intense reflections: 0.1768
• Weighted residual factors for all reflections included in the refinement: 0.1831
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No