Information card for entry 4122363

Structure parameters

• Formula: C69 H48 B2 F20 Ge N4
• Calculated formula: C69 H48 B2 F20 Ge N4
• SMILES: [GeH]1(=C2N(C=CN2[B](N2C=1N(C=C2)C(C)(C)C)(c1ccccc1)c1ccccc1)C(C)(C)C)C(c1ccccc1)(c1ccccc1)c1ccccc1.Fc1c([B-](c2c(F)c(F)c(F)c(F)c2F)(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c(F)c(F)c1F
• Title of publication: Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH](+) Stabilized by a Bis(N-heterocyclic carbene)borate Ligand.
• Authors of publication: Xiong, Yun; Szilvási, Tibor; Yao, Shenglai; Tan, Gengwen; Driess, Matthias
• Journal of publication: Journal of the American Chemical Society
• Year of publication: 2014
• Journal volume: 136
• Journal issue: 32
• Pages of publication: 11300 - 11303
• a: 19.2755 ± 0.0001 Å
• b: 15.9897 ± 0.0001 Å
• c: 20.4354 ± 0.0001 Å
• α: 90°
• β: 100.198 ± 0.001°
• γ: 90°
• Cell volume: 6198.88 ± 0.06 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0412
• Weighted residual factors for significantly intense reflections: 0.1091
• Weighted residual factors for all reflections included in the refinement: 0.1134
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No